碳纳米管导电通路对压电纳米发电机性能的影响Effect of conductive paths of carbon nanotube on performance of piezoelectric nanogenerators
闫静,朱宁,望希言,吕梦蝶,秦跃彬
摘要(Abstract):
为获得高性能压电纳米发电机,提出了在纳米纤维基压电纳米发电机中构筑导电通路的策略,以提高其电荷传输能力。首先,通过静电纺丝技术和煅烧工艺制备钛酸钡(BaTiO_3)纳米纤维,并研究纺丝条件和煅烧工艺对其形貌和结构的影响;其次,通过物理浸泡的方式掺杂不同浓度的多壁碳纳米管(MWCNT),与聚二甲基硅氧烷(PDMS)复合获得柔性压电纳米发电机,探讨MWCNT的含量对压电纳米发电机输出性能的影响。结果表明:纺丝液质量分数为42%、挤出速率为1 mL/h、煅烧温度为1 000℃、升温速率为2℃/min时,获得形貌结构和结晶性良好的BaTiO_3纳米纤维膜;MWCNT质量分数为3%时,压电纳米发电机的综合性能最佳,开路电压和短路电流分别高达23 V和2.6μA,较纯BaTiO_3基压电纳米发电机性能提高4倍。本研究为设计和制备高性能压电纳米发电机提供了新的思路。
关键词(KeyWords): 压电纳米发电机;导电通路;碳纳米管;静电纺丝;钛酸钡
基金项目(Foundation): 国家自然科学基金资助项目(52103267)
作者(Author): 闫静,朱宁,望希言,吕梦蝶,秦跃彬
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