刘玉桂,任元林

• 1:天津工业大学纺织学院

摘要(Abstract)：

综述了目前国内外无卤阻燃环氧树脂(EP)的研究发展状况,重点介绍了磷、氮、硅等阻燃元素对EP的阻燃处理及其有关的阻燃机理和存在的一些问题,如相容性差、耐热性不好和添加量受限等,并介绍了相应的解决方法;最后,对无卤阻燃EP的发展趋势进行了展望,并为国内相关企业提出了一条绿色、高效、复合的发展道路.

关键词(KeyWords)： 无卤;环氧树脂;阻燃

Abstract:

Keywords:

基金项目(Foundation): 天津市自然科学基金资助项目(10JCZDJC22200)

作者(Author): 刘玉桂,任元林

参考文献(References)：

• [1]胡志鹏.我国环氧树脂市场发展综述[J].精细化工原料及中间体,2008,10(1):16-18.
• [2]陈浩,魏明坤.耐高温环氧树脂胶粘剂的研究[D].武汉:武汉理工大学,2009.
• [3]刘志中,王新灵,罗荫培,等.环氧树脂增韧改性研究进展[J].中国塑料,1998,12(6):12-18.
• [4]胡斌.世界环氧树脂的现状及发展趋势[J].国际化工信息,2002,2(1):11-14.
• [5]ELLIS B.The kinetics of cure and network formation[C]//ELLISB.Chemistry and Technology of Epoxy Resin.London:BlackieAcademic and Professional,1993:72-116.
• [6]蔡永源,范华,陈红,等.环氧树脂纳米阻燃材料研究进展[J].热固性树脂,2007,22(6):50-53.
• [7]张跃飞.无卤阻燃剂的开发与应用研究进展[J].塑料,2008,37(4):62-65.
• [8]MAUERER O.New reactive,halogen-free flame retardant sys-tem for epoxy Resins[J].Polymer Degradation and Stability,2005,88(1):70-73.
• [9]LIU Y L,LI S H,LEE H C,et al.Selective reactivity of aro-matic amines toward 5-maleimidoisophthalic acid for prepara-tion of polyamides bearing npheny-imaleimide moieties[J].Reactive and Functional Polymers,2006,66(9):924-930.
• [10]MARTIN C,HUNT B J,EBDONJ R,et al.Synthesis,crosslinking and flame retardance of polymers of boroncontain-ing difunctional styrenic monomers[J].Reactive and Function-al Polymers,2006,66(10):1047-1054.
• [11]LEVCHIK S V,CAMINO G,LUDA M P,et al.Epoxy resinscured with aminophenylmethylphosphine oxide 1:Combustionperformance[J].Polymers for Advanced Technologies,1996,7(11):823-830.
• [12]KUO P L,CHANG J M,WANG T L.Flame-retarding materi-als I.syntheses and flame-retarding property of alkylphos-phate-type polyols and corresponding polyurethanes[J].Jour-nal of Applied Polymer Science,1998,69(8):1635-1643.
• [13]舒万艮,熊联明,刘又年.微胶囊红磷阻燃剂的研究进展[J].中国塑料,2002,16(1):12-14.
• [14]尹月,夏英,蹇锡高.无卤阻燃环氧树脂的研究进展[J].工程塑料应用,2007,35(9):76-79.
• [15]唐敏锋,范晓东,龚彦,等.支化型有机硅/丙烯酸酯共聚乳液的合成及其性能[J].精细化工,2007,24(1):13-16.
• [16]XU W J,ZHU X L,CHENG Z P,et al.Atom transfer radicalpolymerization of n-octyl acrylate under microwave irradiation[J].European Polymer Journal,2003,39(7):1349-1353.
• [17]HOOGENBOOM R,SCHUBERTU S.Microwave-assistedpolymer synt-hesis:Recent developments in a rapidly expand-ing field of research[J].Macromolecular Rapid Communica-tions,2007,28(4):368-386.
• [18]XU Z S,HU X X,LI X Q,et al.Monodispersed PEG-b-PSt-nanoparticles prepared by atom t ransfer radical emulsionpolymerization under microwave irradiation[J].Journal ofPolymer Science:Part A:Polymer Chem istry,2008,46(2):481-488.
• [19]LEVCHIK S V,CAMINO G,LUDA M P,et al.Epoxy resinscured with aminophenylmethylphosphine oxide II.mechanismof thermal decom-position[J].Polymer Degradation and Stabil-ity,1998,60(1):169-183.
• [20]VARMA I K,J AIN P,CHOUDHARY V.Effect of structureon thermal behaviour of epoxy resins[J].Chemistry-A Euro-pean Journal,2003,39(1):181-187.
• [21]GALI M,RONDA J C,SPONTN M,et al.Studies on ther-mal and flame retardant behaviour of mixtures of bis(m-aminophenyl)methylphosphine oxide based benzo-xazine andglycidylether or benzoxazine of bisphenol A[J].Polymer Degra-dation and Stability,2008,93(12):2158-2165.
• [22]XIA X N,LU Y B,ZHOU X.Synthesis of novel phosphorous-containing biphenol,2-(5,5-Dimethyl-4-phenyl-2-oxy-1,3,2-dioxaphosphorin-6-yl)-1,4-benzenediol and it s ap-plication as flame-retardant in epoxy resin[J].Journal of Ap-plied Polymer Science,2006,102(4):3842-3847.
• [23]侯孟华,刘伟区,姚海松,等.无卤阻燃环氧树脂的研究进展[J].现代化工,2005,25(增刊):94-97.
• [24]王海军,陈立新.环氧树脂/含氮阻燃固化剂体系的研究[D].西安:西北工业大学,2006.
• [25]闵玉勤,方琳,张兴宏,等.新型无卤阻燃环氧树脂的合成及性能研究[J].浙江大学学报:理学版,2006,33(4):429-433.
• [26]江蓉,励杭泉.新型含磷阻燃环氧树脂的研制[D].北京:北京化工大学,2007.
• [27]任元林,程博闻,张金树.新型膨胀型阻燃剂阻燃聚丙烯的应用研究[J].高分子材料科学与工程,2008,24(1):116-119.
• [28]党婧,王汝敏,韩小勇,等.新型磷氮协同阻燃环氧树脂的合成与性能[R].2009.
• [29]欧育湘,陈宇,王筱梅.阻燃高分子材料[M].北京:国防工业出版社,2001.
• [30]KANAI H,SULLIVAN V,AUERBACH A.Impact modifica-tion of engineering thermoplastics[J].Joural of Applied PolymerScience,1994,53(5):527-541.
• [31]苏倩倩,刘伟区,侯孟华.有机硅改性提高环氧村脂韧性和耐热性的研究[J].精细化工,2008,25(1):23-27.
• [32]叶春生,陈连喜,白向鸽,等.阻燃型含硅环氧树脂体系的研究进展[J].山西化工,2009,29(3):33-36.
• [33]HSIUE G H,WEI H F,SHIAOS J.Chemical modification ofdicyccopenta diene-based epoxy resins to improre compati-bi1ity and thermal properties[J].Polymer Degradation and Sta-bility,2001,73(2):309-318.
• [34]HSIUE G H,LIU Y L,TSIAO J.Tough,vido-freef,lame re-tardant phenolie mattrix materials[J].Jouml of Applied PolymerScience,2000,78(1)l:-7.
• [35]WU C S,LIU Y L,CHIU Y S.Epoxy resins possessing nameretardant elements from silicom in corporated epoxy compoundcured with phosphoms or nitrogen containing curing agents[J].Polymer,2002,43(15):4277-4284.