活性染料的非均相光催化氧化脱色反应研究Study on decoloration of reactive dyes by heterogeneous photocatalytic oxidation
董文静,董永春,何陆春
摘要(Abstract):
使用自制的微球型非均相光催化剂和过氧化氢对两种中温型活性染料活性红MS和活性蓝B进行非均相光催化氧化脱色反应,重点研究了催化剂数量、光辐射强度、染料浓度和pH值对其脱色反应的影响.结果表明,催化剂数量和光辐射强度的增加能够明显提高染料的脱色率和初始反应速率常数,并且在微球型催化剂的存在下,染料的光催化脱色反应可以在碱性条件下进行,而且脱色率仍然超过50%.但是染料浓度的增加会使其脱色率降低.
关键词(KeyWords): 活性染料;非均相催化剂;光辐射;脱色
基金项目(Foundation): 天津市自然科学基金资助项目(043605911) 天津市高等学校科技发展基金资助项目(20031007) 中国科学院生态环境研究中心环境水化学国家重点实验室开放基金资助项目(2005-01)
作者(Author): 董文静,董永春,何陆春
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