丁晓莉,康长勇,赵红永,王鑫兰,张玉忠,王丽娜

• 1:天津工业大学省部共建分离膜与膜过程国家重点实验室
• 2:中国科学院大连化学物理研究所

摘要(Abstract)：

为获得高的渗透和选择性能,分别以聚乙二醇甲醚丙烯酸酯和双季戊四醇六丙烯酸酯为水相反应单体和油相交联剂,利用界面引发剂在无表面活性剂微乳液油水界面处引发聚合制备中空微球,浇铸形成具有纳米空腔的中空微球膜,并考察了膜内纳米空腔对分离膜气体渗透性和分离性的影响。结果表明:制备的中空微球平均粒径为95 nm,中空结构明显;在高交联剂含量中,中空微球膜的渗透分离性能较壳层材料的本征值都有显著提升,在35℃、0.2 MPa下,CO_2的渗透系数增大4.5倍,且分离系数也有所提升。

关键词(KeyWords)： 界面聚合法;CO_2分离膜;聚合物中空微球;微乳液聚合;气体渗透性

Abstract:

Keywords:

基金项目(Foundation): 国家自然科学基金资助项目(21506160,21776217)

作者(Author): 丁晓莉,康长勇,赵红永,王鑫兰,张玉忠,王丽娜

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