荧光碳点的制备及其在I-检测中的应用Preparation of fluorescent carbon dots and its application in I- detection
庞纪平,江英霞,颜范勇,施锦辉
摘要(Abstract):
为灵敏快速检测碘离子(I~-),以柠檬酸和乙二胺为原料,通过一步水热法合成具有蓝色发射的荧光碳点CDs。通过透射电子显微镜(TEM)、紫外-可见吸收光谱(UV-vis)、傅里叶变换红外光谱(FTIR)和荧光光谱对CDs的结构和光学性能进行表征;并采用CDs检测水样中的I~-,考察其检测效果和淬灭机理。结果表明:I~-可以特异性识别并淬灭CDs的荧光,淬灭机理为静态淬灭;I~-浓度与CDs的荧光强度在20~90μmol/L范围内具有良好的线性响应,检测限为1.743μmol/L;加标回收试验表明该方法可成功应用于真实水样中I~-的检测。
关键词(KeyWords): 碳点;荧光;碘离子;检测;淬灭机理
基金项目(Foundation): 国家自然科学基金资助项目(51678409);; 天津市应用基础和先进技术研究计划资助项目(19JCYBJC19800)
作者(Author): 庞纪平,江英霞,颜范勇,施锦辉
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