可溶性聚酰亚胺规整多孔膜的制备Fabrication of honeycomb membranes from soluble polyimides
王丽华,韩旭彤,田野,丁怀宇,施艳荞
摘要(Abstract):
选用3种可溶性的聚酰亚胺:6FDA-MDA、6FDA-DMMDA和BPADA-DMMDA,在高湿度环境下浇铸形成规整多孔膜结构;研究其规整孔结构的拉伸、吹扫特定形变及其热稳定性,结果发现多孔膜在350℃仍能保持规整结构的稳定.
关键词(KeyWords): 可溶性聚酰亚胺;规整多孔膜;高湿度
基金项目(Foundation): 国家自然科学基金资助项目(20704041);; 中科院分子科学中心创新资助项目(CMS-CX200717);; 国家重点基础研究发展计划资助项目(2003CB615701);; 北京市自然科学基金重点基金资助项目(8071001);; 天津市高等学校科技发展基金计划项目(20071215)
作者(Author): 王丽华,韩旭彤,田野,丁怀宇,施艳荞
参考文献(References):
- [1]JIANG P,HWANG K S,MITTLEMAN D M,et al.Template-directed preparation of macroporous polymers with oriented and crystalline arrays of voids[J].J Am Chem Soc,1999,121:11 630-11 637.
- [2]WIDAWSKI G,RAWISO B,FRANCOIS B.Self-organized honeycomb morphology of star-polymerpolystyrene films[J].Nature,1994,369:387-389.
- [3]STENZEL MH,DAVIS T P,FANE A G,et al.Porous poly-mer films and honeycomb structure made by the self-organiza-tion of well-defined macromolecular structures created by liv-ingradical polymerization techniques[J].AngewChem Ine Ed,2001,40(18):3 428-3 432.
- [4]CHENG C X,TIAN Y,SHI Y Q,et al.Porous polymer filmsand honeycomb structures based on amphiphilic dendronizedblock copolymers[J].Langmuir,2005,21:6 576-6 581.
- [5]CHENG C X,TIAN Y,SHI Y Q,et al.Ordered honeycomb-structured films from dendronized PMA-b-PEO rod-coil blockcopolymers[J].Macromol Rapid Comm,2005,26:1 266-1 272.
- [6]TIANY,JIAOQZ,DINGH Y,et al.The formation of honey-comb structure in polyphenylene oxide films[J].Polymer,2006,47:3 866-3 873.
- [7]WANG L H,TIAN Y,DING H Y,et al.Formation of orderedmacroporous films from fluorinated polyimide by water dropletstemplating[J].EuroPolymJ,2007,43:862-869.
- [8]NISHIKAWA T,NONOMURA M,ARA K,et al.Micropat-terns based on deformation of a viscoelastic honeycomb mesh[J].Langmuir,2003,19:6 193-6 201.
- [9]TIAN Y,LIU S,DING H Y,et al.Formation of deformed honeycomb-patterned films from fluorinated polyimide[J].Polymer,2007,48:2 338-2 344.