翟晓飞,张宇峰,孟建强

• 1:天津工业大学中空纤维膜材料与膜过程省部共建国家重点实验室培育基地

摘要(Abstract)：

介绍了硼的基本性质和硼对植物及人类的危害;重点介绍了海水除硼的几种方法,如反渗透法、电渗析法、离子交换法、萃取法、吸附法等,并对各种方法的分离过程、优缺点、发展趋势等做了分析.

关键词(KeyWords)： 除硼;分离;海水

Abstract:

Keywords:

基金项目(Foundation): 国家自然科学基金资助项目(50903062)

作者(Author): 翟晓飞,张宇峰,孟建强

参考文献(References)：

• [1]BUSANI G.Boron removal in wastewater from ceramic tile fac-tories[J].Ceram Eng Sci Proc,1993,14:457-467.
• [2]RISTIC M D,RAJAKOVIC L V.Boron removal by anion ex-changers impregnated with citric and tartaric acid[J].Sepera-tion Science and Technology,1996,31:2805-2814.
• [3]OZTURK N,KAVAK D.Boron removal form aqueous solutions by adsorption on waste sepiolite and activated waste sepi olite using full factorial design[J].Adsorption,2004,10:245-257.
• [4]刘艳辉,潘献辉,葛云红.反渗透海水淡化脱硼技术研究现状[J].中国给水排水,2008,24(24):91-93.
• [5]WHO.Guidelines for Drinking-Water Quality,Recommenda-tions[S].3rd ed.Geneva:World Health Organization,2004.
• [6]刘茹.海水淡化后处理吸附法除硼研究[D].大连:大连理工大学,2006.
• [7]PRATS D,CHILLON-ARIAS M F,RODRIGUEZ-PASTOR M.Analysis of the influence of pH and pressure on the elimi-nation of boron in reverse osmosis[J].Desalination,2000,128:269-273.
• [8]WHO.Guidelines for Drinking-Water Quality[S].2nd ed.Gene-va:World Health Organization,1993.
• [9]POWER P P,WOODS G W.The chemistry of boron and its speciation in plants[J].Plant and Soil,1997,193:1-13.
• [10]钱国强,林雪,何炳林.硼酸与多羟基化合物的反应及硼选择性树脂[J].离子交换与吸附,1994,10(4):375-382.
• [11]BOUGUERRA W,MNIF A,HAMROUNI B,et al.Boron re-moval by adsorption onto activated alumina and by reverse os-mosis[J].Desalination,2008,223:31-37.
• [12]NADAV N.Boron removal from seawater reverse osmosis per-meate utilizing selective ion exchange resin[J].Desalination,1999,124:131-135.
• [13]GOLDBERG S,GRIEVE C M.Boron adsorption bymaize cell walls[J].Plant Soil,2003,251:137-142.
• [14]PIERUZ G,GRASSIA P,DRYFE R A W.Boron removal from produced water by facilitated ion transfer[J].Desalination,2004,167:416-418.
• [15]PRATS D,CHILLON-ARIAS M F,RODRIGUEZ-PASTOR M.Analysis of the influence of pH and pressure on the elimi-nation of boron in reverse osmosis[J].Desalination,2000,128:269-273.
• [16]HUERTAS Esther,HERZBERG Moshe,ORON Gideon.In-fluence of biofouling on boron removal by nanofiltration and re-verse osmosis membranes[J].J Membr Sci,2008,318:264-270.
• [17]孙国清.吸附法制取低硼海水镁砂的研究[J].海洋科学,1986,10(2):24-28.
• [18]HYUNG Hoon,KIM Jae-Hong.A mechanistic study on boron rejection by sea water reverse osmosis membranes[J].J Membr Sci,2006,286:269-278.
• [19]KOSEOGLU H,KABAY N,Y譈KSEL M,et al.Boron removal from seawater using high rejection SWRO membranes-impact of pH,feed concentration,pressure,and cross-flow velocity[J].Desalination,2008,227:253-263.
• [20]GORENFLO A,BRUSILOVSKY M,FAIGON M,et al.High pH operation in seawater reverse osmosis permeate:First re-sults from the world′s largest SWRO plant in Ashkelon[J].De-salination,2007,203:82-90.
• [21]OO M H,SONG L F.Effect of pH and ionic strength on boron re-moval by RO membranes[J].Desalination,2009,246:605-612.
• [22]MELNIK L,VYSOTSKAJA O,KORNILOVICH B.Boron be-havior during desalination of sea and underground water by electrodialysis[J].Desalination,1999,124:125-130.
• [23]KABAY N,ARAR O,ACAR A,et al.Removal of boron fromwater by electrodialysis:Effect of feed characteristics and inter-fering ions[J].Desalination,2008,223:63-72.
• [24]SIMONNOT M O,CASTEL C,NIKOLAI M.Boron removal from drinking water with a boron selective resin:Is the treat-ment really selective[J].Water Res,2000,34:109-116.
• [25]SENKAL B F,BICAK N.Polymer supported iminodipropylene glycol functions for removal of boron[J].React&Funct Polym,2003,55:27-33.
• [26]KABAY N,SARP S,YUKSEL M.Removal of boron from sea-water by selective ion exchange resins[J].Reactive&Func-tional Polymers,2007,67:1643-1650.
• [27]BICAK N,BULUTCU N,SENKAL B F.Modification of crosslinked glycidyl methacrylate-based polymers for boron-specific column extraction[J].React&Funct Polym,2001,47:175-184.
• [28]SENKAL B F,BICAK N.Polymer supported iminodipropylene glycol functions for removal of boron[J].React&Funct Polym,2003,55:27-33.
• [29]WANG L,QI T,GAO Z.Synthesis of N-methylglucamine modified macroporous poly(GMA-co-TRIM)and its perfor-mance as a boron sorbent[J].React&Funct Polym,2007,67:202-209.
• [30]PILIPENKO A T,GREBENYUK V D,MEL′NICK L-A.Ex-traction of boron compounds from natural waste-water and in-dustrial effluents[J].Khimiyai Tekhnologuiya Vody,1990,12:195-210.
• [31]AYERS P,DUDENEY A W L,KAHRAMAN F.Solvent ex-traction of boron with2-ethyl-1,3-hexanediol and2-chloro-4-(1,1,3,3-tetramethyl butyl)-6-methylol-phenol[J].Jour-nal of Inorganic and Nuclear Chemistry,1981,43:2097-2100.
• [32]BELOVA T P,PARSHIN B E,LATKIN A S,et al.Study of sorption extraction of boron from the geothermal heat carriers[J].Stanford University,2009(2):9-11.
• [33]吴贤熙,李琴琴,黎曼,等.卤水萃取除硼[J].轻金属,1995(7):35-38.
• [34]吴贤熙,汤辉,胡波.卤水除硼萃取剂的反萃研究[J].轻金属,1996(12):44-47.
• [35]SEKI Y,SEYHAN S,YURDAKOC M.Removal of boron from aqueous solution by adsorption on Al 2 O 3 based materials using full factorial design[J].Journal of Hazardous Materials,2006,B138:60-66.
• [36]GARCIA S,CAMACHO E M.Boron removal by means of ad-sorption with magnesium oxide[J].Separation and Purification Technology,2006,48:36-44.
• [37]LIU R,MA W,JIA C Y,et al.Effect of pH on biosorption of boron onto cotton cellulose[J].Desalination,2007,207:257-267.
• [38]RAJAKOVI'C Lj V,RISTI'C M Dj.Sorption of boric acid and borax by activated carbon impregnated with various compounds[J].Carbon,1996,34:769-774.
• [39]LIU H,QING B J,YE X S,et al.Boron adsorption mecha-nism of a hybrid gel derived from tetraethoxysilane and bis(trimethoxysilylpropyl)amine[J].Current Applied Physics,2009,9:e280-e283.
• [40]WANG L,QI T,ZHANG Y.Novel organic-inorganic hybridmesoporous materials for boron adsorption[J].Colloids and Surfaces A:Physicochem Eng Aspects,2006,275:73-78.
• [41]KOSEOGLU H,KABAY N,Y譈KSEL M,et al.The removal of boron from model solutions and seawater using reverse os-mosis membranes[J].Desalination,2008,223:126-133.
• [42]吴水波,潘献辉,初喜章.反渗透淡化除硼的现状和进展[J].环境与健康杂志,2008,25(10):928-930.