阮艳莉,顾祥顺,王天宇

• 1:天津工业大学化学工程与技术学院

摘要(Abstract)：

为开发具有高能量密度的锂氧电池，以PS微球为模板，合成了Uio-66衍生的ZrO_2/C-273复合材料，负载Ru后得到Ru@ZrO_2/C-273正极材料，组装锂氧电池，并对其性能进行了测试。实验结果表明：Ru@ZrO_2/C-273锂氧电池可以有效提高锂氧电池的放电性能，当电流密度为100 mA/g时，具有7 429 m Ah/g的放电比容量，高于Ru@ZrO_2/C锂氧电池的放电比容量（6 164 mAh/g）；随电流密度的不断增加，Ru@ZrO_2/C-273锂氧电池在200 mA/g和300 mA/g的电流密度下分别可以获得6 598 m Ah/g和4 533 mAh/g的放电比容量；在限制比容量为500 mAh/g的循环测试中，Ru@ZrO_2/C-273锂氧电池具有较好的稳定性，可以稳定循环45圈。

关键词(KeyWords)： 锂氧电池;氧电极;Ru;聚苯乙烯

Abstract:

Keywords:

基金项目(Foundation): 国家自然科学基金资助项目（21403153）

作者(Author): 阮艳莉,顾祥顺,王天宇

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